I’ve a dribble of water comming from under the plastic cap whither the valve is open or closed, to see under it is it just a matter of undoing the star-head in the top or will water start pishing out everywhere if its not drained?
go down to B&Q (other DIY stores are available) and buy the valve yourself, go home, turn off the water at the mains, carefully drain the system, remove the valve by undoing the to brass nuts, remove valve, replace with new valve, turn water back on at mains, fill system and then bleed the radiators.
No need to turn mains off, just turn off feed to header tank (small tank) in your loft. I learned a lesson turning mains off n on, busted mains pipe from road to house! One of your rads will have a tap on bottom that you can attach a hose pipe to, run it out in garden, open all the bleed valves when draining down.
Be careful not to miss the cat, you might hit ya plasma screen.